Formation of some transition metal carbides

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A two-stage approach of manufacturing FeAl40 iron aluminides by self-propagating synthesis and pressureless sintering

This is an Accepted Manuscript of an article published by Taylor & Francis Group in Powder Metallurgy on 11 June 2018, available online at https://doi.org/10.1080/00325899.2018.1478778. Under embargo until 11 June 2019.A two-stage sintering process was successfully used to sinter FeAl to densification levels of just above 95% at a temperature of 1300 ºC. In the first stage, mixed iron and aluminium powders were synthesised at 750°C via Self-Propagating High-temperature Synthesis (SHS) to form brittle and porous Fe2Al5. Then the pellets were crushed and milled to various sizes and mixed with iron powders in the nominal composition of FeAl40 and pressurelessly sintered at a higher temperature to obtain a higher densification by taking advantage of the less violent exothermic reaction of Fe2Al5 and Fe. The intermediate and end products in SHS and sintering were characterised by SEM/EDX and XRD. The porosity level of the final FeAl40 product was controlled by the heating rate and powder size, which was also strongly influenced by the temperature, holding time and the ratio of the two powders.Peer reviewedFinal Accepted Versio

Biofuel as an alternative shipping fuel : technological, environmental and economic assessment

© Royal Society of Chemistry 2019Fossil derived fuels available for application within the maritime sector have been dominated by heavy fuel oil (HFO), which is conventionally used in low speed (main) engines, and more refined fuels such as marine diesel oil (MDO), which is consumed in fast or medium speed engines. However, increasing fuel costs and regulatory pressure such as the restrictions placed on sulphur content have increased interest in the use of alternative fuels. A number of alternative fuels have been identified and may be viable for use within the maritime sector including straight vegetable oil (SVO) as an alternative to HFO in low speed engines, biodiesel to replace MDO/MGO in low to medium speed engines and bio-liquefied natural gas (bio-LNG) in gas engines using LNG. The potential sources of biomass feedstocks, conversion pathways and technologies are identified. The key parameters limiting their potential application are examined, in particular, availability, technological development, technical integration, and operational consequences. A proposed solution to overcome these limitations is recommended. The effective implementation of these strategies will enable the more widespread use of biofuels in marine applications, significantly reducing emissions from ships and improving global air quality and also protecting the ecological environment.Peer reviewe

The optimal use of tris-2-ethylhexylamine to recover hydrochloric acid and metals from leach solutions and comparison with other extractants

This document is the Accepted Manuscript version of the following article: Uchenna Kesieme, Andreas Chrysanthou, Maurizio Catulli, and Chu Yong Cheng, ‘The optimal use of tris-2-ethylhexylamine to recover hydrochloric acid and metals from leach solutions and comparison with other extractants’, Journal of Environmental Chemical Engineering, Vol. 6 (2): 3177-3184, April 2018. Under embargo until 1 May 2019. The final, definitive version is available online via: https://doi.org/10.1016/j.jece.2018.05.001This paper describes the use of TEHA for HCl recovery from a leach solution generated by a hydrometallurgical plant. Four organic extractants were tested including TEHA, Alamine 336, Cyanex 923 and TBP. TEHA organic system performed best in terms of acid extraction, stripping and scrubbing efficiency. The successive extraction shows that more than 99% HCl was extracted after three stages of extraction. Scrubbing tests with different A/O ratios at different temperatures were conducted to identify the optimal conditions to separate HCl, Mn and Fe. After scrubbing the loaded organic solution at an A/O ratio of 1:4 and 22 °C, 94–100% of entrained metals were removed in a single contact with only 5.2% acid lost in the loaded scrub liquor. It was found that the phase disengagement time was in the range of 2– 4 min for both extraction and stripping, indicating reasonable fast phase separation. Based on these results from batch tests, it can be expected that after optimisation in a counter current circuit consisting of extraction, scrubbing, selective and bulk stripping, nearly all metals and HCl would be recovered and recycled.Peer reviewe

A review of acid recovery from acidic mining waste solutions using solvent extraction

This is the peer reviewed version of the following article: Uchenna Kesieme, Andreas Chrysanthou, Maurizio Catulli, and Chu Yong Cheng, ‘A review of acid recovery from acidic mining waste solutions using solvent extraction’, Journal of Chemical Technology and Biotechnology, (2018), which has been published in final form at https://doi.org/10.1002/jctb.5728. Under embargo until 1 July 2019. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.The minerals industry is increasingly being forced by regulatory and cost pressures to reduce the amount of liquid acidic waste they produce. This requires a strong focus on waste reduction by recycling, regeneration and reuse. Four mineral acids were examined for recovery from waste acidic solutions including H 2SO 4, HNO 3, HCl, and H 3PO 4. The selection of the optimal extractant for acid recovery was based on extraction, stripping and scrubbing efficiencies. The extractants suitable for the recovery of H 2SO 4 and HCl are in the order of TEHA > Cyanex 923 > TBP > Alamine 336. TEHA has the highest degree of acid extraction and stripping compared with Cyanex 923 and almost 99% of the acid can be stripped. Alamine 336 can extract higher acid (for H 2SO 4 and HCl systems) than Cyanex 923 and TBP. However loaded acid for Alamine 336 system cannot be stripped using water at 60°C. For the recovery of nitric and phosphoric acids from acidic waste effluents, TBP was the best option. This work clearly demonstrates that extractant suitable for acid extraction may not be suitable for its recovery. However such extractant may be applied for the removal of acid from any waste acidic solution sacrificing the back extraction of the loaded acid. The effective implementation of options for acid recovery was examined to improve sustainability in the mineral industry.Peer reviewe

Attributional life cycle assessment of biofuels for shipping: addressing alternative geographical locations and cultivation Systems

Crown Copyright © 2019 Published by Elsevier Ltd. All rights reserved.The purpose of this study is to evaluate a life cycle assessment of straight vegetable oil (SVO) and biodiesel addressing alternative upstream pathways. The pathways are SVO and biodiesel produced in the United Kingdom (UK) using European rapeseed and also, SVO and biodiesel produced in the UK using soybean grain and soybean oil imported from Argentina. Four environmental impact categories have been assessed using the SimaPro (ReCiPe life cycle impact assessment) method: this includes global warming potential (GWP); acidification; eutrophication and particulate matter. Rapeseed based biofuel had the lowest emission impact in terms of GHG emissions. Significant greenhouse gas (GHG) emissions can result from land use change due to the expansion and cultivation of soybean in Argentina. When land use change is not considered, the soy based biofuel system has the lowest GHG impact with more than 70% GHG emission reduction. The GHG emission at cultivation stage far outweighs the impacts of the other life-cycle stages irrespective of the feedstock used for the biofuel production systems. The use of fertilizers and associated soil emissions are the main contributors. The environmental impacts of biofuel can be reduced by avoiding land use change, improving soil management practices and yield, and also optimizing transportation routes. Effective implementation of options for biofuels production were explored to improve sustainability in shipping.Peer reviewe

Self-piercing riveting - a review

Self-Piercing Riveting (SPR) is a cold mechanical joining process used to join two or more sheets of materials by driving a semitubular rivet piercing through the top sheet or the top and middle sheets and subsequently lock into the bottom sheet under the guidance of a suitable die. SPR was originated half century ago, but it only had significant progress in the last 25 years due to the requirement of joining lightweight materials, such as aluminium alloy structures, aluminium-steel structures and other mixed material structures, from the automotive industry. Compared with other conventional joining methods, SPR has a lot of advantages including no predrilled holes required, no fume, no spark and low noise, no surface treatment required, ability to join multilayer materials and mixed materials, and ability to produce joint with high static and fatigue strengths etc. This publication reviews research investigations that have been conducted in the area of self-piercing riveting. The process is described and the effects of the process parameters are discussed. Mechanical properties including static strength, fatigue and crash behaviour are reviewed. Corrosion behaviour is also addressed, while reliable methods for accurate behaviour prediction, process monitoring and non-destructive testing have been identified as the main challenges

Effect of pulsed magnetic treatment on the corrosion of titanium

This is an Accepted Manuscript of an article published by Taylor & Francis in Materials Science and Technology on 17 March 2017, available online: http://www.tandfonline.com/doi/full/10.1080/02670836.2017.1302141.Results of corrosion tests of titanium in the initial state and after treatment using pulsed magnetic field are presented. It is shown that samples after treatment have better corrosion resistance due to the formation of denser and finer corrosion products with better adhesion to the substrate. Samples after treatment have more homogeneous microstructure due to a substantial increase of dislocations which are uniformly distributed. Mechanisms of dislocation multiplication and a model explaining the effect of the treatment on the corrosion are discussed.Peer reviewe

Interface stability between bare, Mn-Co spinel coated AISI 441 stainless steel and a diopside-based glass-ceramic sealant

This document is the Accepted Manuscript version of the following article: A. G. Sabato, A. Crysanthou, M. Salvo, G. Tempura, and F. Smeacetto, ‘Interface stability between bare, Mn-Co spinel coated AISA 441 stainless steel and a diopside-based glass-ceramic sealant’, International Journal of Hydrogen Energy, Vol. 43 (13): 1824-1834, January 2018, made available under the terms of the Creative Commons Attribution-NonCommercial-NoDerivatives License CC BY NC-ND 4.0 ( http://creativecommons.org/licenses/by-nc-nd/4.0/ ), which permits non-commercial re-use, distribution, and reproduction in any medium, provided the original work is properly cited, and is not altered, transformed, or built upon in any way. Under embargo until 16 December 2018. The final, definitive version of this paper is available online at doi: https://doi.org/10.1016/j.ijhydene.2017.11.150.This study is focused on a diopside-based glass-ceramic sealant for solid oxide fuel cells and its compatibility with AISI 441 stainless steel interconnect. The morphological and chemical stability with both bare and Mn–Co spinel coated AISI 441 steel, after 3500 h exposure at 800 °C in air, is reviewed and discussed. Post-mortem samples are morphologically and chemically analysed by SEM-EDS. Reaction products at the glass-ceramic/bare AISI 441 interface, resulting from the reaction of Mg from the sealant and Cr and Mn from the steel, are detected, without affecting negatively the integrity of the joints. In the case of Mn–Co spinel coated AISI 441, interactions between the glass-ceramic and the outer part of the Mn–Co spinel coating, along with crystallization of oxides rich in Si and Mg, are detected, but still no corrosion phenomena are present. The glass-ceramic is found to be compatible with both bare and coated AISI 441.Peer reviewe

Low-velocity impact behaviour of woven laminate plates with fire retardant resin

The understanding of the damage mechanisms for woven laminate plates under low-velocity impact is challenging as the damage mechanisms at the interface of adjacent layers are dominated by the fibre architecture. This work presents an experimental investigation of the behaviour of woven glass and carbon fibre composite laminates in a matrix of fire retardant resin under low-velocity impact. The performance is evaluated in terms of damage mechanisms and force time history curves. Six impact energy levels were used to test standard plates to identify the type of damage observed at various energy levels. Scanning electron microscopy (SEM) along with C-scans were used to characterise the damage. It has been observed that in woven composites, the damage occurs mostly between the fibre bundles and matrix. As the impact energy increases, the failure involves extended matrix cracking and fibre fracture. Moreover, due to the fibre architecture, both the contact forces between bundles of fibres and stretching of the bundles are responsible for the dominant matrix cracking damage mode observed at the low-impact energy level. As the impact energy increases, the damage also increases resulting in fibre fracture. The experimental evidence collected during this investigation shows that for both the carbon fibre and the glass fibre woven laminates the low-velocity impact behaviour is characterised by extended fibre fracture without a noticeable sudden load drop